Aldol addition
An enolate carbon reaches across and draws a new carbon-carbon bond to a carbonyl, the negative charge moving to the alkoxide oxygen as it lands.
An enolate carbon reaches across and draws a new carbon-carbon bond to a carbonyl, the negative charge moving to the alkoxide oxygen as it lands.
A base carries the beta proton away while the leaving group is pushed off the far carbon, and the pi bond draws in between the two as they go.
The two Kekule structures of a benzene ring hand over through the delocalised inner circle and back, the hexagon frame holding still.
A curly arrow sweeps from a donor lone pair to the electrophilic carbon of a carbonyl, its head landing before the arrow clears and sweeps again.
A nucleophile closes on a carbon centre from the back, the spectator bonds inverting through the planar transition state as the leaving group is pushed off the front.
The pi bond of a carbonyl slides towards the oxygen and the partial charges resolve either side of it before the bond relaxes back.
The pi bond of a carboxylate moves from one oxygen to the other while the negative charge moves the other way across the delocalised hybrid.
A dienophile slides into the mouth of a diene and two sigma bonds close the six-membered ring as the old pi bonds retract and a new one draws in.
The proton of an alcohol lifts off the oxygen and its bond retracts, the oxygen carrying a negative charge until the proton returns.
The leaving group ionises off a carbon centre, the planar cation holds inside its dashed shell, and a nucleophile comes in to quench the charge.
A proton and a bulkier group close onto a double bond from either side, the more substituted carbon taking the larger group as the pi bond retracts.
One stereocentre turns over through edge-on and slides onto its mirror image, its wedge becoming a hash so the two stereo bonds refuse to coincide.
A cyclohexane chair inverts through the flat half-chair and the marked substituent hands over from its axial position to the equatorial one.
A zig-zag carbon backbone builds bond by bond over the muted finished formula while the tip marker steps from vertex to vertex.
The rear carbon of a Newman projection turns through a hundred and twenty degrees and back, the strain marker rising each time the bonds eclipse.